These are characters who started off as being normal citizens but later on not only did they become heroes but also became close to Pure Good. These characters used to be normal citizens either due to the fact that they didn't have any intention to be a hero or they were too weak to fight as a hero. Later, these characters gain power and skill to help them fight as a Near Pure Good and ended up being a true hero in the eyes of other characters. Their opposites are those who began as normal citizens but later became Near Pure Evils.
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- Sam Brenner
- Sans (Undertale)
- Saori Joumae
- Sarah (The Legend of Team Brunette)
- Sarah Gerst (John Tamzarain)
- Sasha Waybright
- Shinichi Izumi
- Shoto Todoroki
- Simon Bellamy
- Skips
- Sonic the Hedgehog (Live-Action)
- Spider-Man (2017)
- Spider-Man (Webbverse)
- SpongeBob SquarePants (SpongeBob in Real Life)
- Starlight Glimmer
- Sting Eucliffe
- Subaru Natsuki
- Sunburst
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